Surface characterization of maize-straw-derived biochars and their sorption performance for MTBE and benzene   总被引：2，自引：1，他引：1  

Liwei Xiao  Erping Bi  Beibei Du  Xiaoli Zhao  Chen Xing 《Environmental Earth Sciences》2014,71(12):5195-5205

Biochars generated at various temperatures might show significant differences in sorption for organic contaminants. In this study, a series of biochars, generated from pyrolyzing maize straws at different temperatures, were systematically characterized. The characterization results showed that with increasing pyrolysis temperature, the surface areas, micropore areas and aromaticity of biochars were enhanced. Batch experiments were conducted to study methyl tert-butyl ether (MTBE) and benzene sorption to biochars. The results indicated that the sorption capacity of benzene to biochars was higher than that of MTBE. The higher pyrolyzed temperature of biochars resulted in a stronger sorption affinity for target compounds, and the dominant sorption mechanisms varied for biochars pyrolyzed at different temperatures. The sorption to biochars pyrolyzed at 700 and 800 °C performed a high adsorption capacity, which indicated that they might be a promising sorbent to remove MTBE and benzene from water. Biochar pyrolyzed at 400 °C showed transitional sorption mechanisms from partition to adsorption for MTBE and benzene. Pore-filling was a possible sorption mechanism to biochars pyrolyzed at high temperature.  相似文献   

The comparison analysis of Chinese public perception of earthquakes on different time scales   总被引：1，自引：1，他引：0  

Lei Huang  Weiliang Bao  Kai Chen  Jun Bi 《Natural Hazards》2014,73(2):613-625

China has suffered from severe earthquake disasters in recent years. In order to explore the impact of severe earthquakes on public risk perception on different time scales, four surveys were conducted twice each after the severe Wenchuan and Yushu earthquakes. t tests were performed between two consecutive surveys to explore the change of public risk attitudes. The results demonstrated that after the two severe earthquakes, the public seismic risk acceptance has increased over time, and the comparison between pre- and post-Yushu earthquake illustrated that the severe disaster had more impact on vulnerable population such as females, children and low-income people. Moreover, linear regression models were employed to find the determining factors of public acceptance towards earthquake risks. It was discovered that the public perceived earthquake effect had significant negative relationship with seismic risk acceptance, and public trust towards local government had positive relationship with the risk acceptance. This study could help government to gain better understanding of public mental status and take more effective disaster preparedness measures when preventing and responding to a severe earthquake.  相似文献   

NH₄Cl水溶液的微观结构和宏观物性研究          下载免费PDF全文

张宇  李非  费莉婷  纪志永  赵颖颖  郭小甫  刘杰  王士钊  汪婧  毕京涛  张盼盼  张丁予  袁俊生 《盐湖研究》2022,30(4)

通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH₄Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm_-1^和3100 cm_-1^{附近出现了明显的}N-H作用峰,且随着质量分数的升高,NH₄Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH₄Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH₄₊^-Cl_-^{接触离子对开始成为主要微观作用形式。对}NH₄Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH₄Cl水溶液质量分数的增加而增大。作者推断,NH₄Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH₄₊^-Cl_-^{接触离子对},是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。  相似文献   

2011—2012年近海北上热带气旋对山东半岛风雨影响的分析     

毕玮  万夫敬  高山 《山东气象》2014,34(1):1-5

通过对2011年5号热带风暴“米雷”、9号强热带风暴“梅花”和2012年15号台风“布拉万”共3个近海北上热带气旋的对比分析发现,这类热带气旋给山东半岛造成的影响表现出“先雨后风”的特点。在近海北上热带气旋的影响下,山东半岛的降水基本呈东西向阶梯型分布,同量级的雨带基本呈南北向分布,某地区降水的起止时间、降水量峰值和风速极值的出现时段与热带气旋距该地的距离有一定的对应关系。热带气旋中心位置越过30°N和到达距某地区最近距离的时间对该地降雨的起止时间、降雨峰值和风速极值出现的时段具有一定的指示意义。  相似文献   

水下溢油数值模拟研究   总被引：1，自引：0，他引：1  

陈海波  安伟  杨勇  尤云祥  雷方辉  赵宇鹏  李建伟 《海洋工程》2015,33(2):66-76

基于Lagrange积分法和Lagrange粒子追踪法建立了一个水下溢油数值模型。该溢油模型由两个子模型组成:羽流动力模型和对流扩散模型,其中羽流动力模型用以模拟溢油的喷发阶段和浮力羽流阶段;对流扩散模型用以模拟溢油的对流扩散阶段。通过数值实验,结合实验室水槽实验和水下溢油现场实验的观测资料进行模型验证。实验结果表明,模拟结果与观测资料一致性较好,从而验证了本文溢油模型的合理性和准确性;羽流动力模型为对流扩散模型提供源,海流、海水的垂向密度结构和油滴的直径分布是影响溢油在对流扩散阶段运动和分布的主要因素。  相似文献   

内蒙古科右中旗两类基性岩的年代学、地球化学及其构造意义          下载免费PDF全文

金松  李英杰  钱程  张杨  孟都  杨海波  王博  伍光锋 《地球科学》2022,47(1):342-356

兴蒙造山带东段晚古生代构造演化存在争议,基性岩浆作用是构造演化过程中的良好地质记录. 对贺根山缝合带东段内蒙古科右中旗构造混杂岩带内的杜尔基基性岩和甲哈达基性岩进行了系统的地质特征、岩相学、年代学和地球化学研究. 杜尔基基性岩岩性为枕状玄武岩和辉绿岩,辉绿岩锆石LA-ICP-MS U-Pb年龄为348.3±2.6 Ma,为低钾拉斑玄武系列,相对富集LILE,亏损Nb、Ta等高场强元素. 甲哈达基性岩岩性主要为玄武岩,锆石U-Pb年龄为317.6±3.0 Ma,为钙碱性系列,同样具有HFSE亏损和LILE富集的特点,与杜尔基基性岩相比更加富集LILE和LREE. 结合贺根山缝合带早石炭世蛇绿岩及洋内俯冲作用的研究成果,认为从杜尔基基性岩到甲哈达基性岩的演化,可能指示了古亚洲洋东段早-晚石炭世洋内俯冲的渐进过程,洋内弧从不成熟向逐渐成熟演化.   相似文献   

塔里木盆地库车坳陷西秋古隆起的形成及其演化   总被引：1，自引：0，他引：1       下载免费PDF全文

余海波  漆家福  师骏  张玮  曹淑娟  范绳  孙统  杨向阳 《地质科学》2015,50(2):524-535

重力异常资料显示,库车坳陷南缘西秋构造带深层发育有基底隆起。本文通过地震资料解释确认了西秋构造带深层占隆起的结构,分析了占隆起的形成和演化过程。西秋构造带南侧边缘存在一条区域性基底断裂,断裂北侧新生界下伏中生界、古生界明显减薄或地层缺失,总体上表现为断背斜形态的古隆起构造。结合区域构造演化分析认为,泥盆纪~石炭纪(D-C)塔里木克拉通边缘隆升、二叠纪-三叠纪(P-T)受南天山负荷影响产生的克拉通边缘压陷的构造演化过程中,西秋构造带处于"跷跷板"式地壳升降运动的"支点"部位,发育古隆起和基底卷入高角度断层,晚期南天山隆升向南斜向推挤的挤压剪切应力场使古隆起边界断层复活,基底断裂活动并在新生界之下形成冲断隆起。  相似文献   

Numerical Simulation of Crack Growth and Coalescence in Rock-Like Materials Containing Multiple Pre-existing Flaws   总被引：1，自引：1，他引：0  

X. P. Zhou  J. Bi  Q. H. Qian 《Rock Mechanics and Rock Engineering》2015,48(3):1097-1114

  相似文献   

西藏北冈底斯扎独顶A型花岗岩锆石U-Pb年代学、地球化学及其地质意义   总被引：3，自引：2，他引：1       下载免费PDF全文

解 龙 顿 都朱利东  尼玛次仁  杨文光陶 刚 李 超 何 碧 和 源 《中国地质》2015,(5):1214-1227

西藏北冈底斯早白垩世花岗岩分布广泛;扎独顶岩体作为其中的一个典型代表,其分布广泛,呈岩基型式产出,在岩性上属二长花岗岩。在岩石化学上扎独顶岩体具有富Si O2(70.05%~74.97%)和K2O(4.09%~5.35%),贫Ca O(0.93%~2.19%)、Ti O2(0.22%~0.52%)和Al2O3(12.81%~14.24%)的特征;属于准铝质-弱过铝质(A/CNK=0.99~1.0)高钾钙碱性系列。岩体稀土元素总量偏高(∑REE=199.36×10-6~247.91×10-6),相对富集轻稀土元素(LREE/HREE=5.82~6.88),Eu负异常明显(δEu=0.30~0.45),球粒陨石标准化分布模式呈向右缓倾的V型。微量元素显示其富集Rb、Th、K、Zr和Hf,亏损Nb、Ta、Sr、Ba、P和Ti,(Zr+Nb+Ce+Y)平均值为427.63。全岩锆石饱和温度(828~838°C)表明岩浆形成温度高。上述岩石地球化学特征表明扎独顶岩体为A型花岗岩。扎独顶岩体LA-ICP-MS锆石U-Pb年龄为(103.8±1.0)Ma,表明其形成于早白垩世晚期;在构造判别图解上位于碰撞后的A2型花岗岩区,是在碰撞后岩石圈伸展背景下,由于软流圈物质上涌导致岩石圈地幔与壳源熔体部分熔融并经历过一定程度的混合作用而形成的。  相似文献   

Characteristics and Main Controlling Factors of Tight Oil Reservoir in the Jimsar Sag of Junggar Basin   总被引：1，自引：0，他引：1  

BAO Haijuan  HE Wenjun  FEI Liying  JIA Xiyu  ZHENG Menglin  YANG Haibo  GGUO Xuguang 《《地质学报》英文版》2015,89(Z1):182-183

<正>1 Introduction Jimsar sag covers about 1278 km2 in the south of the eastern uplift of Junggar basin.It is a half graben depression area in which the west,south and north is controlled by faults(Fig.1),and is tilting uplift to the east.It deposited Permian,Triassic,Jurassic,the Cretaceous and Cenozoic strata chronologically.The thickness of Lucaogou Formation is about 200 m to 350 m,it is the  相似文献